YU Liangang. Identification Characteristic of A New Ivory Imitation Material[J]. Journal of Gems & Gemmology, 2017, 19(3): 24-34. DOI: 10.15964/j.cnki.027jgg.2017.03.003
Citation: YU Liangang. Identification Characteristic of A New Ivory Imitation Material[J]. Journal of Gems & Gemmology, 2017, 19(3): 24-34. DOI: 10.15964/j.cnki.027jgg.2017.03.003

Identification Characteristic of A New Ivory Imitation Material

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  • Received Date: May 14, 2017
  • A fantastic simulated products similar to ivory in appearance such as graining and texture have arised in Guangzhou jewelry wholesale market in recent years, bringing about new tasks for identification of ivory and related accessories.In this paper, three circular tags are used as test samples, and conventional physical property test, knife scratch, hot needle spine, microscopic observation of texture, infrared spectrum analysis have been studied. The author contrasts the differences in internal and external characteristics with the other imitations such as mammoth teeth, hippo teeth, nut ivory, animal bones, celluloid, plastic products and the real ivory.The routine test results showed that the simulated material has the physical parameters of refractive index 1.48(point measurement), relative index 1.22, and it emerges complete roll sheets while being scratched, and comes into hollow pinprick, granular powder residue, white colour while contacting with hot needle. Microscopic observation indicated that the grain lines arrange in a gradual transition by coarse, irregular to fine from the center to the edge on the circular samples' surface. The central is the rows of big wavy lines, and the middle layer is a rough concentric ripple, and the outer layer is fine concentric ripples. Each graining line changes from narrow to wide in width, and its boundaries are vague, extending in the curving and independent Z-shaped way. Furthermore, the texture and structure characteristics inside the simulated products are completely consistent with the outside, and lack of Retzius layers, cross-rhomb patterns and overall concentric structure of ivory. Infrared spectrometry indicated that the stimulated products has uniform material composition, without being coating. The main three strong infrared absorption peaks located at 2 920、1 728、1 278 cm-1. None of vibration absorption spectrum peak is related to collagen amide linkage and PO43-, and drasticly differs from ivory. In brief, this stimulated material is a kind of macromolecule alkyd resin. Compared with the previous imitations, this stimulated material is characterized with its unique texture such as gradual transition of thickness and density, clear hierarchy and incomplete concentric ripple layered structure. Furthermore, colour, luster, density and refractive index can be used as an auxiliary basis for identification.
  • [1]
    张虎才.我国东北地区晚更新世中晚期环境变化与猛犸象-披毛犀动物群绝灭研究综述[J].地球科学进展,2009:24(1):49-58.
    [2]
    亓利剑,周征宇,廖冠林,等.猛犸象牙与象牙的微生长结构及红外吸收光谱的差异性[J].宝石和宝石学杂志,2010, 12(3):3-4.
    [3]
    张蓓莉.系统宝石学[M].2版.北京:地质出版社,2006:554-558.
    [4]
    陆光月,杨景兴,李法杰,等.仿象牙材料的研究[J].塑料科技,1989,15(3):37.
    [5]
    任洪祥,毛兰娟,林文瑛,等.工艺品软膜的制作技术[J].今日科技,1993,2(2):10-11.
    [6]
    欧阳健明,陈德志.自组装膜调控下生物矿物晶体的生长[J].化学进展,2005,17(3):563-572.
    [7]
    黄兆龙,郭俊明,刘卫,等.胶原及其生物矿化物的红外光谱特征[J].红河学院学报,2003,1(1):42.
    [8]
    翁诗甫.傅里叶变换红外光谱分析[M].北京:化学工业出版社,2010:323-325.
    [9]
    吴晓,张钧,鲁先虎,等.荧光光谱学在象牙与猛犸象牙鉴定上的应用[J].宝石和宝石学杂志,2013,15(3):51-52.
    [10]
    彭世文,刘高魁.矿物红外光谱图集[M].北京:科学出版社,2007:463-467.
    [11]
    刘国杰.气干性水性醇酸树脂涂料改性实例[J].中国涂料,2014,12(7):12-18.
    [12]
    刘迎新,曾力华,徐伟箭,等.自干型改性水溶性醇酸树脂的研制[J].现代涂料与涂装,2006,12(6):4-6.
    [13]
    赵庆玲,王锋,胡剑青,等.环氧改性水性醇酸树脂的制备[J].热固性树脂,2012,6(2):32-36.

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