Citation: | LI Xingtong, XU Chang, ZHENG Jinyu, SHEN Hongtao, Shen Andy Hsitien, ZHANG Qian. Gemmological and Mineralogical Characteristics of Apatite from Madagascar with Directional Inclusions[J]. Journal of Gems & Gemmology, 2024, 26(S1): 104-107. |
In this study, the apatites containing directional arrangement inclusions from Madagascar were investigated using microscope, Raman spectroscopy, scanning electron microscope (SEM), X-ray energy dispersive spectroscopy (EDS), and magnetic test. Microscopic observation results show that there are abundant needle-like inclusions with metallic luster, which are parallel to c-axis of the apatite crystal. These inclusions could produce the cat's eye effect of apatite under the light. EDS results reveal that Fe and O elements are rich in the exposed region of inclusion, suggesting that it is a type of iron oxide. Raman spectroscopy displays a weak peak at 662 cm-1, which can be attributed to the A1g vibration mode of magnetite. The hysteresis loop test confirms that the inclusions are ferromagnetic substances, indicating that the needle-like inclusions are magnetite.
[1] |
Wüthrich A, Weibel M. Optical theory of asterism[J]. Physics and Chemistry of Minerals, 1981, 7(1): 53-4. doi: 10.1007/BF00308202
|
[2] |
Yu J, He X, Lu Z. Cause analysis of chatoyancy of sapphires from Shandong, China[J]. RSC Advances, 2019, 9(42): 24 420-24 427.
|
[3] |
Schmetzer K, Bernhardt H-J, Gilg H A. Characterization of oriented inclusions in cat's-eye, star and other chrysoberyls[J]. Journal of Gemmology, 2016, 35(1): 28-54. doi: 10.15506/JoG.2016.35.1.28
|
[4] |
Schmetzer D, Kiefert D, Hänni P. Asterism in beryl, aquamarine and emerald—An update[J]. Journal of Gemmology, 2004, 29(2): 65-71. doi: 10.15506/JoG.2004.29.2.65
|
[5] |
Schmetzer K, Bernhardt H-J, Kiefert L. Star garnets and star garnet cat's-eyes from Ambatondrazaka, Madagascar[J]. Journal of Gemmology, 2002, 28(1): 13-24. doi: 10.15506/JoG.2002.28.1.13
|
[6] |
Barot N, Graziani G, Gübelin E, et al. Cat's-eye and asteriated gemstones from East Africa[J]. Journal of Gemmology, 1995, 24(8): 569-580. doi: 10.15506/JoG.1995.24.8.569
|
[7] |
Johnson C. Cat's-eye apatite from Namibia[J]. Journal of Gemmology, 2014(34): 191.
|
[8] |
Mauthner M, Ottaway T. Gem apatite localities[J]. Rocks & Minerals, 2015, 90(3): 260-269.
|
[9] |
Kammerling R, Koivula J. Greenish-blue cat's-eye apatite[J]. Gems & Gemology, 1990, 26(3): 230.
|
[10] |
Rakovan J, Laurs B M. Large cat's-eye apatite from Madagascar[J]. Journal of Gemmology, 2016, 35(3): 186-189.
|
[11] |
Kammerling R, Koivula J, Johnson M, et al. Cat's-eye apatites from Madagascar[J]. Gems & Gemology, 1995(31): 205-206.
|
[12] |
Roedder E. Fluid inclusions[M]. Boston: De Gruyter, 1984.
|
[13] |
O'shea D, Bartlett M, Young R. Compositional analysis of apatites with laser-Raman spectroscopy: (OH, F, Cl) apatites[J]. Archives of Oral Biology, 1974, 19(11): 995-1 006. doi: 10.1016/0003-9969(74)90086-7
|
[14] |
Taddei P, Tinti A, Gandolfi M G, et al. Vibrational study on the bioactivity of Portland cement-based materials for endodontic use[J]. Journal of Molecular Structure, 2009(924): 548-554.
|
[15] |
Shebanova O N, Lazor P. Raman spectroscopic study of magnetite (FeFe2O4): A new assignment for the vibrational spectrum[J]. Journal of Solid State Chemistry, 2003, 174(2): 424-430. doi: 10.1016/S0022-4596(03)00294-9
|
[16] |
Cornell R M, Schwertmann U. The iron oxides: structure, properties, reactions, occurrences, and uses[M]. Weinheim: Wiley-vch, 2003.
|
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