稀土矿物及宝石材料的变色效应与颜色量化的研究

A Study on Colour-Change Effect and Colour Quantification of Rare Earth Minerals and Gem Materials

  • 摘要: 一些稀土致色的矿物具有显著的变色效应。本研究以天然及合成稀土致色矿物样品(水碳钠钇石、磷钇矿、氟碳铈矿及Nd掺杂合成萤石)为研究对象,通过电子探针(EPMA)、激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)及紫外-可见光谱测试分析,系统性探究了不同发光原理光源(荧光灯和LED)及其不同色温的光源对矿物样品变色效应的影响。结果显示,水碳钠钇石和磷钇矿主要致色离子均以Er3+为主,同时Nd3+,Sm3+,Dy3+和Tm3+也有致色贡献;氟碳铈矿致色离子为Nd3+和Pr3+。基于CIE 1976 L*a*b*色空间的颜色计算结果,与实际样品照片对比发现,光源发光原理对矿物呈色影响较为显著,而相同发光原理光源中色温变化的影响效果相对有限。荧光灯下,水碳钠钇石呈桃红色调,LED灯下则呈淡橙黄色;在荧光灯下,磷钇矿呈粉橙色,LED灯下呈黄色;在荧光灯下,氟碳铈矿为橙色,LED灯下为黄色;在荧光灯下,Nd掺杂合成萤石接近无色,而LED灯下呈紫色。当前珠宝玉石分级标准中对光源的规定较为模糊,质检机构实际使用光源未统一规范,不同光源光谱特性的差异可能导致分级时对颜色评价不一致。因此,本研究旨在提供一种对照明体选择与评价的科学方法基础,呼吁在相关国家标准制定时应更加重视对照明体的选择与规定。

     

    Abstract: Some REE-coloured minerals exhibit strong colour-change effect. Using electron probe microanalysis (EPMA), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and UV-Vis spectra analysis, this study systematically investigates the effects of light sources with different emission mechanisms and colour temperatures on the colour-change effect of natural and synthetic REE-coloured mineral samples, including shomiokite-(Y), xenotime-(Y), bastnäsite-(Ce), and Nd-doped synthetic fluorite. The results show that both shomiokite-(Y) and xenotime-(Y) are mainly coloured by Er3+, while Nd3+, Sm3+, Dy3+ and Tm3+ also contribute to the colouration. The bastnäsite-(Ce) is coloured by Nd3+ and Pr3+. Based on colour calculations in the CIE 1976 L*a*b* colour space and comparisons with actual photographs, this study demonstrates that, among the investigated light sources, the light emission mechanism has a significant impact on the colour presentation of mineral samples, while changes in colour temperature within the same emission mechanism have relatively limited effects. Under fluorescent lamps, shomiokite-(Y) exhibits a pinkish hue, whereas under LED lamps, it appears pale orange-yellow. Xenotime-(Y) shows a pinkish-orange colour under white fluorescent lamps and yellow under white LED lamps. Bastnäsite-(Ce) appears orange under fluorescent lamps and yellow under LED lamps. Nd-doped synthetic fluorite is nearly colourless under fluorescent lamps, but displays a purple colour under LED lamps. Analysis results of light sources used in quality supervision and inspection institutions and rules in relevant national standards indicate that the regulations for light sources in gemstone grading standards are relatively vague, and differences in the spectral characteristics of light sources may lead to inconsistencies in colour evaluation when grading. Therefore, a greater emphasis should be placed on the selection and specification of illuminants in relevant national standards. This study aims to provide a scientific methodological basis for the selection and evaluation of light sources.

     

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