加拿大多色水晶的宝石学及谱学特征

Gemmological and Spectroscopic Characteristics of Multi-coloured Crystal from Canada

  • 摘要: 产自加拿大桑德贝具有颜色分带的多色水晶(商业名称“极光23水晶”),最初发现于加拿大安大略省苏必利尔湖北岸的桑德贝地区。目前,国内外对该多色水晶的研究较少,缺少相关的文献记载。本研究借助显微成像、红外光谱及拉曼光谱技术对多色水晶的宝石学与光谱特征进行测试,从宝石学特征、包裹体形态组合以及矿物组成3个角度进行分析并开展产地对比研究,以期为加拿大多色水晶的鉴定及后续探索提供理论支撑。研究结果显示,加拿大多色水晶整体颜色为紫色、深褐色至深红色,折射率为1.545~1.553,相对密度为2.64~2.65,长波或短波紫外光下均为惰性,符合α-石英族矿物特征;原石多以晶簇产出,尖端晶面可见三角形生长丘,包裹体主要集中在白色和深紫色区域,形态多样,如片状、块状、簇状、短针状,部分区域可见多种包裹体混合排列,长度为10~1 000 μm、宽度为1~10 μm。红外光谱分析显示,其特征吸收峰位于400~600 cm-1、700~800 cm-1及1 100~1 200 cm-1;拉曼光谱分析显示,黑色包裹体和红色包裹体均为赤铁矿,金色簇状包裹体为针铁矿,金属光泽立方块状包裹体为黄铁矿,样品表面红色层由同心环状密集排列的赤铁矿包裹体聚集在水晶内部近表层构成。

     

    Abstract: The multi-coloured crystal from Thunder Bay, Canada, commercially known as "Auralite 23 Crystal", is a rare crystal variety first discovered in Thunder Bay area along the northern shore of Lake Superior in Ontario, Canada. To date, there have been few international studies on this type of multi-coloured crystal, and no relevant domestic literature on Canadian amethyst has been reported. In this study, microscopic imaging, infrared spectroscopy and Raman spectroscopy techniques were employed to systematically analyze the gemmological characteristics, inclusion morphology and mineral components, along with comparative research on its origin, in order to provide theoretical support for further investigation of Canadian multi-coloured crystals. The overall colour of the multi-coloured crystal samples from Canada exhibited purple, dark brown, to deep red tones, and polished samples showed a refractive index of 1.545- 1.553, with the relative density ranging from 2.64-2.65, and no fluorescence was detected under long-wave or short-wave ultraviolet radiation, consistent with the characteristics of α-quartz group minerals.Rough stones typically occur as crystal clusters, with triangular growth hills visible on the crystal terminations. Inclusions are mainly concentrated in white and dark purple zones, displaying diverse morphological features such as sheet-like, block-like, cluster-like, and short acicular forms. In some areas, multiple inclusions are mixed, with lengths ranging from 10-1 000 μm and widths from 1-10 μm. Infrared spectroscopy revealed characteristic absorption peaks at 400-600 cm-1, 700-800 cm-1, and 1 100-1 200 cm-1. Raman spectroscopy indicated that black and red inclusions are hematite, golden cluster-like inclusions are goethite, metallic cubic block inclusions are pyrite, and the red surface layer consists of densely aggregated concentric-ring hematite inclusions within the near-surface crystal.

     

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