辰砂及其仿制品的鉴别与定名探讨

Identification and Nomenclature of Cinnabar and Its Imitation

  • 摘要: 辰砂在我国中医药、书画等领域具有悠久的应用历史,现今主要作为首饰出现于珠宝玉石市场。为解决市场定名混乱的问题,本次研究收集了辰砂及其加工制品、仿制品,采用常规宝石学测试、红外光谱、X射线荧光光谱等技术手段进行测试分析。结果显示,当测试样品具有343 cm-1处红外特征吸收峰,主要成分为HgS,抛光表面呈金刚光泽,颜色为暗红色或鲜红色时,可定名其为辰砂;当测试样品为少量胶结物黏结辰砂颗粒,整体仍具有金刚光泽时,可定名其为拼合辰砂;当测试样品由大量胶结物包裹辰砂碎块或碎屑组成,整体呈树脂光泽时,可定名其为再造辰砂;当测试样品不含辰砂颗粒或主要成分无HgS,但外观与辰砂相似时,应定名其为仿辰砂。含有辰砂的珠宝玉石应依据国家标准GB/T 16552和GB/T 16553的现行有效版本定名。

     

    Abstract: Cinnabar has been historically utilized in traditional Chinese medicine, calligraphy, and painting. Now it is primarily marketed as jewelry. To address the issue of non-standard nomenclature in the market, this study analyzed natural cinnabar along with its processed products and imitations. The samples were analyzed using conventional gemmological test methods, infrared spectroscopy, and X-ray fluorescence spectroscopy. The results indicated that the dark-red to vivid-red minerals with an infrared characteristic absorption peak at 343 cm-1, that predominantly composed of HgS, and displayed an adamantine luster on polished surfaces, should be identified as cinnabar. Samples that composed of cinnabar particles with minimal adhesive, retaining an overall adamantine luster, should be classified as composite cinnabar. Those encapsulated by abundant binding agents and exhibiting resinous luster, should be categorized as reconstructed cinnabar. Materials that mimic the appearance of cinnabar but contain neither HgS as the primary component nor cinnabar particles, should be designated as cinnabar imitations. Jewelry and jade containing cinnabar should be named in accordance with the current effective versions of the national standards GB/T 16552 and GB/T 16553.

     

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