湖南砂矿金刚石的成分和结构特征及其多源性启示

Composition and Structural Characteristics of Alluvial Diamonds from Hunan Province and Implications of Their Multiple Sources

  • 摘要: 我国重要金刚石产地之一的湖南砂矿金刚石,其系统性研究综述尚显匮乏。本文系统地梳理了湖南砂矿金刚石的成分及结构特征。资料显示,湖南金刚石以ⅠaAB型为主,Ⅰb和Ⅱa型占比相对较高;含氮量以及氮聚集程度呈现明显不均一性;晶面花纹和颜色丰富,晶体形态多样,多呈现曲面外观,指示该金刚石上升到地壳的过程中经历了复杂环境;内部生长结构多样,包括简单生长结构及复杂的斑杂生长结构和似玛瑙状生长结构;碳同位素组成(δ13C)范围较宽,与榴辉岩型金刚石更为一致,揭示其碳源及形成机制有别于华北克拉通金刚石;包裹体种类有橄榄岩系列和榴辉岩系列组合,深部包裹体来源值得进一步探索。上述特征表明,湖南金刚石具有多源性、多期次、高复杂性的特点。不同金刚石个体具有一定来源个性,难以依据单一金刚石特征确认“整体”湖南金刚石的产地来源特征,需通过不断挖掘现有金刚石中所携带的杂质特征,特殊结构和包裹体信息,从而完善对湖南金刚石产地来源的认识。

     

    Abstract: Alluvial diamonds from Hunan Province, one of China's key diamond-producing regions, remain insufficiently summarized in terms of systematic research. This study synthesizes the composition and structural characteristics of alluvial diamonds from Hunan Province.The researches indicate that diamonds from Hunan Province are mainly ⅠaAB type, with relatively high proportions of Ⅰb and Ⅱa types. The distribution of nitrogen content and the degree of nitrogen aggregation exhibit significant heterogeneity. Crystal surfaces exhibit diverse patterns and colours, accompanied by significant variations in morphology, including curved morphologies, indicating a complex environmental history during their ascent to the crust. Internal growth structures vary from simple growth structures, and complex mottled growth structures and "agate-like" structures. The carbon isotopic compositions (δ13C) exhibits a broad range, aligning more closely with eclogitic-type diamonds than those from the North China Craton, implying distinct carbon sources and formation mechanisms. Inclusion types include peridotitic and eclogitic suites, while the origin of deep mantle-derived inclusions warrants further investigation. These features collectively indicate that the diamonds from Hunan Province possess multisource origins, multistage evolution, and high complexity. Individual diamonds exhibit unique source-specific signatures, precluding definitive determination of their collective origin traits based on isolated characteristics. Advancing the understanding of provenance of the diamonds from Hunan Province requires systematic extraction of genetic information including impurities, special structures and inclusions from existing samples.

     

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