含粉色或红色矿物和田玉的宝石矿物学特征

Gemmological and Mineralogical Characteristics of Nephrite Containing Pink or Red Minerals

  • 摘要: 近期,在珠宝市场上出现了含粉色或红色矿物的和田玉,其颜色商业上常称为“樱花粉”和“胭脂红”。前人认为粉色是由于含Mn绿帘石或黝帘石所致,目前未见含红色矿物和田玉的报道。本研究采用常规宝石学仪器、拉曼光谱仪、扫描电子显微镜、紫外-可见光谱仪和激光剥蚀电感耦合等离子体质谱仪对含粉色或红色矿物和田玉的矿物组成及颜色成因进行了探讨。结果表明,含粉色或红色矿物和田玉样品的致色矿物分别为含Mn3+的黝帘石和含Mn3+的斜黝帘石,其颜色均主要由在M3位Mn3+的d-d跃迁导致。经拉曼光谱测试,次要矿物碳氢镁石和自然硫首次在含红色矿物和田玉样品中发现。

     

    Abstract: Recently, nephrite containing pink or red minerals has appeared on the market, the former is called "Cherry Blossom Pink", and the latter is called "Carmine". For nephrite containing pink minerals, some researchers suggested that the pink colour may be caused by Mn-bearing epidote, and some agreed that it might be caused by Mn-bearing zoisite. At present, no report can be found on nephrite containing red minerals. In this study, conventional gemmological test instruments, Raman spectroscopy, scanning electron microscope, UV-Vis spectroscopy and laser ablation inductively coupled plasma mass spectroscopy (LA-ICP-MS) were used to investigate the mineral components and colour origin of these two kinds of nephrite. The results showed that the colouring minerals in these kinds of nephrite samples are Mn3+-bearing zoisite(pink) and Mn3+-bearing clinozoisite(red), respectively, and their colours were mainly caused by the d-d transition of Mn3+ at the M3 site. By Raman spectroscopy, two minor minerals, nesquehonite and native sulphur, were found in the nephrite containing red minerals for the first time.

     

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