墨西哥黄绿色磷灰石的包裹体特征

Inclusion Characteristics of Yellow-Green Apatite from Mexico

  • 摘要: 墨西哥黄绿色磷灰石因其独特的地球化学研究意义,被称为“Durango”磷灰石,但目前对此种磷灰石的包裹体研究资料较少。以墨西哥黄绿色磷灰石为研究对象,采用显微照相机、拉曼光谱仪以及冷热台显微测温技术对其进行全面的包裹体研究,旨在丰富墨西哥黄绿色磷灰石的包裹体特征和产地特征。结果表明,墨西哥黄绿色磷灰石中包裹体丰富,以流体包裹体最为突出,根据相态详细分为Ⅰ型纯液相包裹体、Ⅱ型气液两相包裹体(包括Ⅱa和Ⅱb型)和Ⅲ型含子矿物的多相包裹体(包括Ⅲa、Ⅲb和Ⅲc型);拉曼光谱结果显示硬石膏和重晶石两种子矿物成分以及CO2的1 285 cm-1处的特征峰;Ⅰ型和Ⅱ型流体包裹体对应的成矿流体温度分别变化于106.5~169.6 ℃和218.5~546.5 ℃范围内,为低盐度流体(0.18~10.73 wt% NaCl eqv),Ⅲ型流体包裹体对应成矿流体温度大于600 ℃,盐度大于26.30 wt% NaCl eqv,说明磷灰石形成时流体包裹体为非均一状态下捕获;固体包裹体包括黑色假象赤铁矿、绿色透辉石、透明长石,以假象赤铁矿出现频率最高。经推测,墨西哥磷灰石的成矿压力及成矿深度分别为39.23~150.70 MPa、1.31~5.02 km。

     

    Abstract: The yellow-green apatite from Mexico is known as "Durango" apatite because of its unique geochemical significance. However, there is less information on its inclusions. Taking the yellow-green apatites from Mexico as the research objects, a comprehensive inclusion study was carried out using the microcamera, Raman spectrometer, and hot and cold table microthermometry, aiming at enriching the inclusions characteristics and origin features of the yellow-green apatites from Mexico. The results show that the yellow-green apatites from Mexico are rich in inclusions, especially fluid inclusions, which can be divided into typeⅠpure liquid inclusions, typeⅡgas-liquid two-phase inclusions (including types Ⅱa and Ⅱb) and type Ⅲ multiphase inclusions with daughter minerals (including types Ⅲa, Ⅲb and Ⅲc) according to phase states. Raman spectrometer detects two daughter mineral components of anhydrite and barite as well as the characteristic 1 285 cm-1 peak of CO2. The temperature of ore-forming fluid corresponding to typeⅠand Ⅱ fluid inclusions varies in the range of 106.5-169.6 ℃ and 218.5-546.5 ℃, respectively, and they are low-salinity fluids (0.18-10.73 wt% NaCl eqv). The ore-forming fluid corresponding to type Ⅲ fluid inclusions are with temperatures > 600 ℃ and salinities > 26.30 wt%, indicating that fluid inclusions were trapped in non-uniform state when apatite was formed. The solid inclusions include black pseudohematite, green diopside and transparent feldspar, with pseudohematite appearing most frequently. The metallogenic pressure and depth of apatite from Mexico are estimated to be 39.23-150.70 MPa and 1.31-5.02 km, respectively.

     

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