Adv Search
Volume 17 Issue 2
Mar.  2015
Turn off MathJax
Article Contents
Abstract
References
XING Yingying, QI Lijian, MAI Yicheng, XIE Minghui. FTIR and13C NMR Spectrum Characterization and Significance of Amber from Different Origins[J]. Journal of Gems & Gemmology, 2015, 17(2): 8-16.
Citation: XING Yingying, QI Lijian, MAI Yicheng, XIE Minghui. FTIR and13C NMR Spectrum Characterization and Significance of Amber from Different Origins[J]. Journal of Gems & Gemmology, 2015, 17(2): 8-16.
shu

FTIR and13C NMR Spectrum Characterization and Significance of Amber from Different Origins

  • 1. Gemmologocal Institute, Guangzhou College of South China University of Technology, Guangzhou 510800, China;

  • 2. Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China;

  • 3. Shcool of Ocean and Earth Science, Tongji University, Shanghai 200092, China

More Information
  • Received Date: June 08, 2014
    Graphical Abstract
    • Abstract
  • Some pieces of amber from different origins and copal resin were tested and analyzed by FTIR and13C NMR.From testing results，amber from difference origins has the basically similar FTIR characteristics，such as absorption bands at 2 930，2 870 cm-1caused by the saturated C—H bond stretching vibration，and the corresponding infrared absorption bands 1 460～1 443 cm-1and 1 384～1 375 cm-1induced by CH2—CH3bending vibration. Compared with the amber，FTIR characteristics of copal resin show infrared absorption weak band at 3 080 cm-1induced by C═CH2antisymmetric stretching vibration，infrared absorption bands at 1 645 cm-1induced by C═C stretching vibration and infrared absorption band at 890 cm-1caused by C—H out of plane deformation vibration.Analyses of FTIR and 13C NMR characterize amber from different origins and natural resin with relative different petrochemical maturity degree. The age of amber from Burma，Dominica，Liaoning and Mexico reduce in turn．Peaks of 13C NMR spectrum at δ=14×10-6～18×10-6 and δ=179×10-6～220×10-6 only appear in copal resin，showing that the petrochemical maturity is relatively low．This paper finally concludes the FTIR and 13C NMR spectrum characterization and significance of amber from different origins．
    • FullText(HTML)
    • References (17)
  • [1]
    张蓓莉.系统宝石学[M]. 2版.北京:地质出版社, 2006:542-547.
    [2]
    杨剑芳, 董小萍, 郭力, 等.琥珀的化学研究进展[J]. 北京中医杂志, 2002, 21(4):245-248.
    [3]
    王微枢.辽宁抚顺煤田琥珀的矿物学特征[J]. 国外非金属矿与宝石, 1990(5):47-50.
    [4]
    杨一萍, 王雅玫.琥珀与柯巴树脂的有机成分及其谱学特征综述[J]. 宝石和宝石学杂志, 2010, 12(1):16-22.
    [5]
    郭时清, 严小敏, 孙尧俊, 等.中国琥珀的剖析[J]. 复旦学报(自然科学版), 1991, 30(3):271-274.
    [6]
    Abduriyim A, Hideaki K, Yukihiro Y, et a1.Characterization of-green amber with infrared and nuclear magnetic resonance spectroscopy[J]. Gems&Gemology, 2009, 45(3):9-13.
    [7]
    徐红奕, 杨如增, 李敏捷, 等.琥珀的有机元素分析[J]. 宝石和宝石学杂志, 2007, 9(1):12-14.
    [8]
    李坤, 申晓萍.琥珀及其主要仿制品的红外光谱鉴定[J]. 中国测试, 2013, 39(2):33-36.
    [9]
    张倩怡.琥珀及其仿制品特征红外吸收光谱研究[J]. 超硬材料工程, 2013, 25(4):54-58.
    [10]
    Lambert J B.Carbon functionalities in amber[J]. Science, 1982, 217(2):55-57.
    [11]
    Michael F, Lamprecgt I.Thermal investigations of amber and copal[J]. Thermochimica Acta, 2007, 458(1-2):162-170.
    [12]
    赵瑶兴, 孙祥玉.有机分子结构光谱鉴定[M]. 北京:北京科学出版社, 2009:20-57.
    [13]
    麦义城.缅甸琥珀FTMIR光谱表征及13C NMR解析[D]. 上海:同济大学, 2013.
    [14]
    彭国桢, 朱莉.多米尼加琥珀[J]. 宝石和宝石学杂志, 2006, 8(3):32-35.
    [15]
    亓利剑, 周征宇, 廖冠琳, 等.热压条件下绿色柯巴树脂的聚化行为及13C NMR表征[J]. 宝石和宝石学杂志, 2010, 12(3):9-13.
    [16]
    杨一萍, 王雅玫.琥珀与柯巴树脂的有机成分及其谱学特征综述[J]. 宝石和宝石学杂志, 2010, 12(1):16-22.
    [17]
    亓利剑, 袁心强, 陈铭.处理琥珀和树脂的ESR行为及13C NMR表征[J]. 宝石和宝石学杂志, 2003, 5(2):1-6.
    • Related Articles

Catalog

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (88) PDF downloads (26) Cited by()
    Related
    Email alert RSS
    二维码

    Supported by Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return