ZHAN GJian, CHEN Hua, LU Tai-jin, QIU Zhi-li, WEI Ran. Distribution Characteristics and Surface Microtopography of Nitrogen Platelets in Diamond Crystals from Shandong Province, China[J]. Journal of Gems & Gemmology, 2011, 13(3): 7-11,22.
Citation: ZHAN GJian, CHEN Hua, LU Tai-jin, QIU Zhi-li, WEI Ran. Distribution Characteristics and Surface Microtopography of Nitrogen Platelets in Diamond Crystals from Shandong Province, China[J]. Journal of Gems & Gemmology, 2011, 13(3): 7-11,22.

Distribution Characteristics and Surface Microtopography of Nitrogen Platelets in Diamond Crystals from Shandong Province, China

More Information
  • Received Date: April 11, 2011
  • In order to study the distribution characteristics of nitrogen platelets in diamond crystals from Shandong Province, China, 116 pieces of gem quality diamond crystal samples are investigated by using FTIR.The surface microstructures related to the nitrogen platelets are observed by differential interference microscope.The results show that 80.2% of the diamond samples contain nitrogen platelets.The stripe-like etch figures parallel to[100] directions on {111} planes are discovered on the surfaces of several brown octahedral diamond samples.These etch figures lie parallel to each other and vary in size.The microanalysis of the {111} planes show that there are stronger IR absorption peaks at 1 359-1 375 cm-1in the diamond samples, revealing the existence of huge quantities of nitrogen platelets.Judging from their appearances and IR spectra, the formation of the stripe-like etch figures parallel to[100]directions on{111}planes may result from selective etching of the platelets.
  • [1]
    Field J E.The properties of diamond[M].London:Academic Press, 1979.
    [2]
    Antonelli A, Nunes Ricardo.A stacking-fault based microscopic model for platelets in diamond[J].American Physical Society, APS March Meeting, 2005,(3):21-25.
    [3]
    池际尚,路凤香,刘永顺,等.中国原生金刚石成矿地质条件研究[M].武汉:中国地质大学出版社, 1996.
    [4]
    罗声宣,任喜荣,朱源,等.山东金刚石地质[M].济南:山东科学技术出版社, 1999.
    [5]
    王萍,李国昌.山东蒙阴金刚石的晶体形态和晶面特征[J].矿产与地质, 1999, 13(4):253-256.
    [6]
    Davies G.Decomposing the IR absorption spectra of diamonds[J].Nature, 1981,(290):40-41.
    [7]
    Taylor W R, Jaques A L, Ridd M.Nitrogen-defect aggregation characteristics of some Australasian diamonds:Timetemperature constraints on the source regions of pipe and alluvial diamonds[J].American Mineralogist, 1990, 75(11-12):1 290-1 310.
    [8]
    (苏)奥尔洛夫.金刚石矿物学[M].北京:中国建筑工业出版社, 1977.
    [9]
    徐柏森,杨静.实用电镜技术[M].南京:东南大学出版社, 2008.
    [10]
    Zaitsev A M.Optical properties of diamond[M].Berlin and Heidelbergn:Springer-Verlag, 2001.
    [11]
    Clark C D, Davey S T.One-phonon infrared absorption in diamond[J].Journal of Physics C:Solid State Physics, 1984, 17(6):1 127-1 140.
    [12]
    Bursill L A, Glaisher R W.Aggregation and dissolution of small and extended defect structures in type Ia diamond[J].American Mineralogist, 1985, 70(5-6):608-618.
    [13]
    Kiflawi I, Bruley J, Luyten W, et al.'Natural'and'manmade'platelets in type-Ia diamonds[J].Philosophical Magazine Part B, 1998, 78(3):299-314.
    [14]
    Evans T, Qi Zengdu.The kinetics of the aggregation of nitrogen atoms in diamond[J].Proceedings of the Royal Society of London.A, 1982, 381(1 780):159-178.
    [15]
    Lang A R.A proposed structure for nitrogen impurity platelets in diamond[J].Proceeding of the Physics Society, 1964, 84(6):871-876.
    [16]
    Berger S D, Pennycook S J.Detection of nitrogen at{100}platelets in diamond[J].Nature, 1982,(298):635-637.
    [17]
    Hutchison J L, Bursill L A.Fresnel fringe contrast of faceted voids within gem quality diamond[J].Journal of Microscopy, 1983,(131):63-66.
    [18]
    Bursill L A.Small and extended defect structures in gemquality type I diamonds[J].Endeavour, 1983, 7(2):70-77.
    [19]
    Brozel M R, Evans T, Stephenson R F.Partial dissociation of nitrogen aggregates in diamond by high temperature-high pressure treatments[J].Proceedings of the Royal Society of London.A, 1978, 361(1 704):109-127.

Catalog

    Article Metrics

    Article views (102) PDF downloads (14) Cited by()
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return