Adv Search
Volume 21 Issue 1
Dec.  2018
Turn off MathJax
Article Contents
Abstract
References
Related Articles
XIN Chenxing, LI Yan, HAO Liang, FENG Zuying, XIONG Wei. Fabrication of Biodegradable UV-Curable Resin via Stereolithography for Wearable Jewelry[J]. Journal of Gems & Gemmology, 2019, 21(1): 49-59. DOI: 10.15964/j.cnki.027jgg.2019.01.006
Citation: XIN Chenxing, LI Yan, HAO Liang, FENG Zuying, XIONG Wei. Fabrication of Biodegradable UV-Curable Resin via Stereolithography for Wearable Jewelry[J]. Journal of Gems & Gemmology, 2019, 21(1): 49-59. DOI: 10.15964/j.cnki.027jgg.2019.01.006
shu

Fabrication of Biodegradable UV-Curable Resin via Stereolithography for Wearable Jewelry

  • Gemmological Institute, China University of Geosciences, Wuhan 430074, China

More Information
  • Received Date: June 29, 2018
    Graphical Abstract
    • Abstract
  • Additive manufacturing (AM), also known as three-dimensional printing (3D Printing), has made remarkable achievements in electronics, industrial design, architecture, medical application, automotive industry and aerospace, etc. In recent years, it gradually emerged in jewelry industry. This paper develops a new formulation of biodegradable UV-cured resin with biosafety for stereolithography apparatus (SLA) and performs a comprehensive analysis of its 3D printability, mechanical properties, internal and external conditions via viscometer, thermogravimetric analysis, mechanical testing machine, Fourier transform infrared spectrometer (FITR) and scanning electron microscope, etc. The results indicate that the formulation possesses low viscosity as well as proper thermal stability at room temperature which is suitable for 3D printing of jewelry. The tensile strength and flexural strength changes with the accuracy of 3D printing. FITR result shows that N-O stretching vibration peak indicates that the resin reacts with diluent completely. Under the microscope, the number of bubbles and powder decrease with the 3D printing precision increasing. Scanning electron microscope shows that the higher the precision, the more uneven the fracture surface and the better the machine properties. Finally, the biodegradable UV-cured resin is used for jewelry printing and various series of jewelry are obtained.
    • FullText(HTML)
  • Figure  1.  Infrared spectra of the main minerals in common ancient Chinese jade artifacts
    DownLoad: Full-Size Img PowerPoint
    Table  1.  Confusion matrix, accuracy, precision, and recall of the test set in the nephrite origin discrimination model
    预测结果/% 精确率(%) 召回率(%) F1分数/%
    敖汉 贝加尔 春川 敦煌 溧阳 龙溪 罗甸 马衔山 马鬃山 青海 新疆 岫岩
    敖汉 100 0 0 0 0 0 0 0 0 0 0 0 100 100 100
    贝加尔 0 100 0 0 0 0 0 0 0 0 0 0 78.6 100 88.0
    春川 0 0 100 0 0 0 0 0 0 0 0 0 100 100 100
    敦煌 0 0 0 100 0 0 0 0 0 0 0 0 100 100 100
    溧阳 0 0 0 0 100 0 0 0 0 0 0 0 100 100 100
    龙溪 0 0 0 0 0 100 0 0 0 0 0 0 100 100 100
    罗甸 0 0 0 0 0 0 100 0 0 0 0 0 100 100 100
    马衔山 0 0 0 0 0 0 0 80 0 0 20 0 100 80.0 88.9
    马鬃山 0 0 0 0 0 0 0 0 100 0 0 0 100 100 100
    青海 0 0 0 0 0 0 0 0 0 100 0 0 100 100 100
    新疆 0 10.3 0 0 0 0 0 0 0 0 89.7 0 92.9 89.7 91.2
    岫岩 0 0 0 0 0 0 0 0 0 0 0 100 100 100 100
     | Show Table
    DownLoad: CSV
    • References (12)
  • [1]
    王延庆, 沈竞兴, 吴海全. 3D打印材料应用和研究现状[J]. 航空材料学报, 2016, 36(4): 89-98. https://www.cnki.com.cn/Article/CJFDTOTAL-HKCB201604013.htm
    [2]
    Chia H N, Wu B M. Recent advances in 3D printing of biomaterials[J]. Journal of Biological Engineering, 2015, 9(1): 4. doi: 10.1186/s13036-015-0001-4
    [3]
    Wong K V, Hernandez A. A review of additive Manufacturing[J]. Isrn Mechanical Engineering, 2012(2): 30-38. http://www.onacademic.com/detail/journal_1000036958954810_0272.html
    [4]
    Wang J, Goyanes A, Gaisford S, et al. Stereolithographic (SLA) 3D printing of oral modified-release dosage forms[J]. International Journal of Pharmaceutics, 2016, 503(1—2): 207-212. doi: 10.1016/j.ijpharm.2016.03.016
    [5]
    洪啸吟, 孟怀东. 立体光刻技术[J]. 影像科学与光化学, 1997 (3): 276-286. https://cdmd.cnki.com.cn/Article/CDMD-10140-1016096685.htm
    [6]
    Weng Z X, Zhou Y, Lin W X, et al. Structure-property relationship of nano enhanced stereolithography resin for desktop SLA 3D printer[J]. Composites Part A, 2016(88): 234-242. http://www.onacademic.com/detail/journal_1000038950387210_64b9.html
    [7]
    寇亮亮, 薛惠芸, 廖毅彬, 等. 液态光学胶的固化收缩率的研究[J]. 厦门大学学报(自然版), 2014, 53(3): 378-382. https://www.cnki.com.cn/Article/CJFDTOTAL-XDZK201403018.htm
    [8]
    Melchels F P, Feijen J, Grijpma D W. A poly(D, L-lactide) resin for the preparation of tissue engineering scaffolds by stereolithography[J]. Biomaterials, 2009, 30(23): 3 801-3 809. http://www.researchgate.net/profile/Ferry_Melchels/publication/24393502_A_poly(DL-lactide)_resin_for_the_preparation_of_tissue_engineering_scaffolds_by_stereolithography/links/00b4951c25d08cb459000000.pdf
    [9]
    黄笔武, 谢王付, 杨志宏. 一种3D打印立体光刻快速成型光敏树脂的制备及性能研究[J]. 功能材料, 2014, 45(24): 24 100-24 104. https://www.cnki.com.cn/Article/CJFDTOTAL-GNCL201424021.htm
    [10]
    于翔, 王延伟, 徐茜, 等. 一种光固化快速成型用亚光光敏树脂及其制备方法, 2017.
    [11]
    Atai M, Watts D C, Atai Z. Shrinkage strain-rates of dental resin-monomer and composite systems[J]. Biomaterials, 2005, 26(24): 5 015-5 020. doi: 10.1016/j.biomaterials.2005.01.022
    [12]
    Karmarkar A, Chauhan S S, Modak J M. Mechanical properties of wood-fiber reinforced polypropylene composites: Effect of a novel compatibilizer with isocyanate functional group[J]. Composites Part A Applied Science & Manufacturing, 2007, 38(2): 227-233. http://forest.ckcest.cn/d/hxwx/AVkJEOo249MUqoKBM23K.html
    • Related Articles

  • Related Articles

    [1]SHAO Tian, LYU Fanglin, LUO Heng, LIU Taiqiao, Shen Andy Hsitien. Comparison between Greenish-Blue and Orange Phosphorescence in HPHT Synthetic Diamond[J]. Journal of Gems & Gemmology, 2024, 26(S1): 6-9.
    [2]ZHANG Zhiqing, Andy Hsitien Shen. Analysis of Amber Components by Matrix-Assisted Laser Desorption/Ionisation Time-of-Flight Mass Spectrometry[J]. Journal of Gems & Gemmology, 2022, 24(4): 1-9. DOI: 10.15964/j.cnki.027jgg.2022.04.001
    [3]ZHANG Chaoqun, CHEN Meihua, ZOU Yu. Effect of Temperature Control Gradient and Time on the Quality of Synthetic Jadeite[J]. Journal of Gems & Gemmology, 2022, 24(1): 58-67. DOI: 10.15964/j.cnki.027jgg.2022.01.007
    [4]SONG Zhonghua, TANG Shi, ZHU Wenfang, GAO Bo, LI Yujie, LU Taijin. Spectral Characteristic of Natural and HPHT-Grown Type Ⅰb Diamonds[J]. Journal of Gems & Gemmology, 2021, 23(6): 51-57. DOI: 10.15964/j.cnki.027jgg.2021.06.005
    [5]LI Jianhua, HU Junheng, SU Panzhe, LU Jihong, ZANG Jinhao, WANG Yuchang. Progress in Synthesis and Analysis of Lab-Grown Diamond[J]. Journal of Gems & Gemmology, 2021, 23(6): 12-24. DOI: 10.15964/j.cnki.027jgg.2021.06.002
    [6]SHAO Tian, LYU Fanglin, ZHANG Jinqiu, ZHANG Haikun, Shen Andy Hsitien. Phosphorescence Characteristic on Boron-Doped HPHT Synthetic Diamond Produced in China[J]. Journal of Gems & Gemmology, 2019, 21(S1): 1-3. DOI: 10.15964/j.cnki.027jgg.2019.S1.001
    [7]JIA Qiong, CHEN Meihua. Luminescence Characteristic and Fluorescence Spectrum of HPHT-Treated and Irradiated Diamond[J]. Journal of Gems & Gemmology, 2018, 20(3): 1-8. DOI: 10.15964/j.cnki.027jgg.2018.03.001
    [8]SONG Zhonghua, LU Taijin, KE Jie, SU Jun, TANG Shi, GAO Bo, HU Ning, ZHANG Jun, WANG Dufu. Identification Characteristic of Large Near-Colourless HPHT Synthetic Diamond from China[J]. Journal of Gems & Gemmology, 2016, 18(3): 1-8.
    [9]LAN Yan, LIANG Rong, LU Taijin, ZHANG Tianyang, SONG Zhonghua, MA Hong, MA Ying. Identification Characteristic of Near-Colourless Melee-Sized HPHT Synthetic Diamond in Chinese Jewelry Market[J]. Journal of Gems & Gemmology, 2015, 17(5): 12-17.
    [10]YANG Ye, CHEN Mei-hua, WEI Peng, HU Wei. A Study on Sol-gel Technique of HTHP Synthetic Jadeite[J]. Journal of Gems & Gemmology, 2012, 14(2): 13-18.

Catalog

    Figures(19)  /  Tables(3)

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (402) PDF downloads (38) Cited by()
    Related
    Email alert RSS
    二维码

    Supported by Beijing Renhe Information Technology Co., Ltd.  Baidu Analytics

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return