LI Jianjun, QI Yanling, SHAN Guangqi, LI Dongmei. Two Pieces of Sapphires Treated by Be and Ti Multiple Diffusion[J]. Journal of Gems & Gemmology, 2014, 16(2): 27-31.
Citation: LI Jianjun, QI Yanling, SHAN Guangqi, LI Dongmei. Two Pieces of Sapphires Treated by Be and Ti Multiple Diffusion[J]. Journal of Gems & Gemmology, 2014, 16(2): 27-31.

Two Pieces of Sapphires Treated by Be and Ti Multiple Diffusion

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  • Received Date: July 29, 2013
  • The laboratory of the Gold and Diamond Testing Center of China(NGDTC)encountered two pieces of Be and Ti diffused sapphires.When the facet junctions near the culets of two stones are observed in immersion,colour appears darker,which means two stones have been diffused by Ti element.Chemical analysis by the laser ablation inductively coupled plasma mass(LA-ICP-MS)shows the Be concentrations are 23,14ppma respectively in the surface layers of two stones,which indicates they have been also diffused by Be element.As we all know,Be diffusion of corundum must always be carried out in a highly oxidizing atmosphere,but Ti diffusion process should undergo in a reducing atmosphere.Considering the possible course,the authors believe that the stones have been heated through multiple procedures,which makes it hard to identify the diffusion because common evidence of Be diffusion has been deleted.As advisable disclose,it is enough to state that the stone is dif-fused.The trade does not need to focus too much on the roles of Be and/or Ti in these stones when they are in market.
  • [1]
    Abduriyim A,Kitawaki H.Applications of laser ablation-in-ductively coupled plasma-mass spectrometry(LA-ICP-MS)to gemology[J].Gems &Gemology,2006,42(2):98-118.
    [2]
    Emmett J L,Scarratt K,McClure S F,et al.Beryllium diffusion of ruby and sapphire[J].Gems &Gemology,2003,39(2):84-135.
    [3]
    陈涛,杨明星.Be扩散处理、热处理和天然双色昌乐蓝宝石的宝石学特征与鉴别[J].光谱学与光谱分析,2012,32(3):651-654.
    [4]
    郭涛,邵洁涟,颜慰萱.山东昌乐蓝宝石的颜色成因与优化[J].矿物学报,1993,13(3):286-292.
    [5]
    胡明月,何红蓼,詹秀春,等.基体归一定量技术在激光烧蚀-等离子体质谱法锆石原位多元素分析中的应用[J].分析化学,2008,36(7):947-953.
    [6]
    亓利剑,曾春光.一种体色呈蓝色的铍扩散处理蓝宝石[J].宝石和宝石学杂志,2008,10(1):1-4.
    [7]
    吴瑾光.近代傅里叶变换红外光谱技术及应用(下卷)[M].北京:科学技术文献出版社,1994:129-155.
    [8]
    余晓艳.山东蓝宝石的宝石矿物学特征[J].岩矿测试,1999,18(1):41-45.
    [9]
    张蓓莉.系统宝石学[M].2版.北京:地质出版社,2006:193-232.

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