一种商业名为“金丝玉”的矿物学特征

Mineralogical Characteristics of“Jinsiyu”(Quartz)

  • 摘要: 采用X射线粉末衍射仪、X射线荧光光谱仪、扫描电子显微镜及紫外-可见分光光度计等现代测试仪器,对商业名为“金丝玉”的样品矿物学特征及颜色成因进行了研究。X射线粉末衍射分析结果显示“金丝玉”的主要组成矿物为石英。X射线荧光光谱揭示“金丝玉”中含有Al、Fe、Mg、K、Mn、Na、Ti和P等元素;扫描电子显微镜观察结果表明“金丝玉”为微米级石英构成的集合体,其红色调可能由Fe的均匀分布导致;能谱分析结果显示“金丝玉”样品含有微量的C;紫外-可见分光光度计测试结果表明,Fe主要以赤铁矿和针铁矿的形式赋存在“金丝玉”中,二者的联合作用致使样品呈褐红色调。

     

    Abstract: A kind of marron jade with its commercial name"Jinsiyu"was newly found in Xinjiang.A sample was collected and mineralogical characteristics and coloration of the sample were investigated by X-ray diffraction,X-ray fluorescence,scanning electron microscope and ultraviolet-visible spectrophotometer.This maroon and translucent jade has a typical glass luster. Under transmission light,some tiny filaments are observed distinctly in irregular arrangement, Conventional gemmological test results show that the refractive index of the jade is 1.54 (point measurement) and the specific gravity is 2.64 and the hardness is bigger than that of a steel knife. Accordingly.the main mineral component of sample is preliminarily inferred to be quartz.The patterns of X-ray diffraction show the sample has peaks at 4.25 Å(100), 3.33 Å(101).2.45 Å(110),2.28 Å(102), 2.23 Å(111), 2.12 Å(200), 1.98 Å(201) and so on, It reveals that the main mineral component of the sample is quartz.The result of X-ray fluorescence demonstrates that the main chemical composition of the sample is Si. It also contains a small quantity of Al and trace amount of Fe, Mg, K, Mn, Na, Ti and P.Scanning electron microscope result shows that angular quartz particles constitute the sample. Most of the quartz particles is bigger than 5 microns, and some smaller than 2 microns. The result of the energy dispersive spectrometer tells that the sample contains trace amount of C. Surface scanning analysis shows that evenly dispersing Fe leads to the maroon tone.The coloration theory was studied by using ultraviolet-visible spectrophotometer. The diffuse reflection spectrum reveals that the existence of Fe in the sample is mainly in two forms:hematite and goethite. It is because the combination of the two coloration minerals that leads to the maroon colour of the sample. In addition, the high content of hematite is the main reason of the partial red colour.

     

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