块状水钙铝榴石玉的点状绿研究及其鉴别

STUDY AND IDENTIFICATION OF POINT-LIKE GREEN IN MASSIVE HYDROGROSSULAR JADE

  • 摘要: 根据显微镜下、红外光谱和X射线衍射的研究,表明块状水钙铝榴石玉的主要矿物成分是水钙铝榴石,并有含量不等的透辉石和方解石等。它的折射率为1.720左右,相对密度为3.40~3.50。在水钙铝榴石矿物中分布有密集程度不等的点状绿。这些点状绿多呈圆形或泪滴状,其长径约为0.1~1.0mm。每个点状绿的中心都有大小为0.01~0.50mm的黑斑。多数黑斑中心由一个黑点组成,但也有由两个或两个以上的黑点构成。黑斑与包绕其的绿色圈之间的界线分明,且绿色圈与其外的水钙铝榴石间的界线也较明显。绿色圈的成分为绿泥石;中心黑斑在偏光镜下放大250×时为半透明,400×时则为透明。能谱研究表明,黑斑可能是由含一定量铁的硅酸盐矿物组成,但铁含量比外圈的绿泥石稍高。黑斑的形成是由于水钙铝榴石在绿泥石化过程中析出的铁质富集在点状绿的中心所致。这种点状绿是鉴定块状水钙铝榴石玉的最重要特征之一。

     

    Abstract: The study on massive hydrogrossular by means of polar microscope, infrared spectra and X ray shows that it consists mainly of hydrogrossular, with a little amount of diopside and calcite. Its refraction index is about 1. 720 and its relative density 3. 40~3.50.Point-like green about 0.1~1.0 mm in grain size is distributed in hydrogrossular and shows the shape of circle or tear. The center of point-like green consists of black point whose grain diameter is 0.01~0, 50 mm. The center of almost all point-like green consists of only one black point. The boundary between the black point and its surrounding green circle is clear. The point-like green has also a clear boundary with the hydrogrossular encircling it. Black point in green circle center is translucent under thin section by magnification 250×, transparent by magnification 400×. The result of energy spectrum analysis shows that black point consists of silicate mineral containing higher amount of iron than chlorite outside the circle. The black point results from aggregation of iron produced by chloritization of hydrogrossular. The point-like green is an important character of hydrogrossular.

     

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