钻石高温高压处理技术

HPHT Treatment Technology of Diamond

  • 摘要: 天然Ⅰa型褐色钻石在高温高压条件下通过加载塑性变形的强度,促进晶体内部位错的增殖和滑移,使钻石由褐色改变为黄绿色;高温高压有助于Ⅱa型褐色钻石克服其所处的势垒,促使钻石中的位错发生攀移、重组、湮灭,使之修复至塑性变形前的初始稳定状态,并最大限度地恢复其原本无色的面貌。天然灰色钻石在高温高压条件下发生了石墨—钻石的同质多象转变,微细石墨包裹体消失,灰色调消除,钻石透明度显著增强

     

    Abstract: High pressure and high temperature (HPHT) intensify the plastic deformation of natural Ⅰa brown diamonds and make the dislocation in the crystal multiply and slippage, thus the brown transforms into the yellow-green. HPHT provide the lattice defects in Ⅱa brown diamonds with sufficient potential energy for movement, recombination and annihilation, and restore them to the stable state and original colourlessness. HPHT-processing of the natural gray diamonds containing graphite and a new model of the colour enhancement are proposed. It is proposed that there occurs a polymorphous transformation from graphite inclusions to diamonds during HPHT-processing. As a result, microscopic graphite inclusions disappear completely, thus removing the gray component and making diamond crystals more transparent (colourless).

     

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