琥珀热压处理新方法及鉴定特征

New Hot Pressing Treatment of Amber and Its Identification Characteristic

  • 摘要: 近年来, 随着琥珀市场的竞争愈演愈烈, 为了降低加工成本、减少原料损耗, 市场上出现了一种新型的琥珀热压处理技术, 即将等同圆珠重量的波罗的海琥珀原料进行简单的不规则切割后, 利用不同直径圆珠模具, 经过加热、施压, 一次成形, 可批量生产出圆珠, 减少了传统圆珠加工的流程和成本。这种新技术处理的琥珀品种可以细分为金绞蜜、蜜蜡、白蜜及带原皮的白花蜜等, 粒径从12~20 mm或以上不等, 常见15 mm以上的大珠。其外观与天然琥珀极其相似, 不易识别, 破坏了琥珀市场有序良性的发展。为了认识和鉴别琥珀热压处理的新方法、新产品, 利用宝石偏光显微镜、红外光谱仪、光致发光光谱仪等仪器测试方法, 揭示了新型热压处理琥珀的鉴别特征。研究发现: (1)经过热压处理的部分琥珀圆珠, 后期会慢慢释放内压力回弹变形, 外观形状不圆, 表面可出现或浅或深的龟裂纹。新型热压琥珀的稳定性差, 若在100 ℃下加热8-10分钟琥珀圆珠即可恢复至热压前的不规则形貌。(2)转动热压处理的金绞蜜和蜜蜡圆珠时, 部分表面会呈现与琥珀光泽不同的似丝绢状光泽, 推测是因为受到定向压力产生的微细流纹所致; 透明度相对较高的琥珀, 在偏光显微镜下通过消光现象, 可以观察到原始刻面棱及模具咬合痕迹; 热压过程会改变天然蜜蜡流动纹的流动状态, 使其出现紊乱、不连续分布等现象。(3)热压处理琥珀的红外光谱与天然琥珀对比有细微的差异, 显示有热处理琥珀的红外光谱特征, 尤其是C=C双键上C-H面外弯曲振动所致的888 cm-1的吸收峰大多消失或减弱; 光致发光光谱发光峰位基本一致, 只是在同等的测试条件下, 发光强度有所减弱, 鉴定意义不大。

     

    Abstract: In recent years, the competition of amber market is increasingly fierce, and a new amber processing technology has emerged in the market in order to reduce the processing cost and the loss of rough amber materials. After a simple and irregular cutting of the rough Baltic amber materials with the same weight as the beads, different diameter bead molds are used to heat and apply pressure to produce the beads in mass production, and the technology reduces the process and cost of traditional beads because of its one cycle formation. The amber varieties treated by this new technology can be subdivided into translucent golden twisted beeswax amber, beeswax amber, white beeswax amber, and white flora pattern beeswax amber with original skin, with particle sizes ranging from 12-20 mm or above, and commonly above 15 mm. Its appearance is extremely similar to that of natural amber, which is difficult to identify and undermine the orderly and healthy development of the amber market. In order to understand and identify this new method and products, this research reveals the identification characteristics of this new type of hot-pressed amber by means of gemstone polarizing microscope, infrared spectroscopy and photoluminescence spectroscopy.The results show that: (1) Some hot-pressed amber beads will slowly release internal pressure and rebound and deform after being placed under natural conditions for 3-6 months, with a non-circular appearance and shallow or deep turtle cracks on the surface. Besides, the stability of the beads treated by this hot pressing is poor. If heated at 100 ℃ for 8-10 minutes, the amber beads will exhibit their irregular morphology before hot pressing treatment.(2) When turning the hot-pressed translucent golden amber and beeswax amber beads, part of the surface show a silk-like luster that is different from the amber/resin luster, which is speculated to be caused by the micro flow lines generated by directional pressure. Through the extinction phenomenon under the polarizing microscope, the original engraved edges and occlusal marks caused by mold can be observed in amber with higher transparency. (3) There are slight differences in the infrared spectra of hot-pressed amber comparing to that of natural amber, indicating the infrared spectral characteristics of heat treated amber, especially the absorption peak of 888 cm-1 caused by the out of plane bending vibration of C-H on the C=C double bond, which mostly disappears or weakens. The photoluminescence peak positions of photoluminescence spectrum are basically consistent, but under the same test conditions, the luminescence intensity is weakened, and the identification is of little significance.

     

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