青金石的宝石矿物学及谱学特征研究

Gemmological and Mineralogical Characteristics of Lapis Lazuli

  • 摘要: 青金石是一种历史悠久的蓝色玉石,在人类文明史中占有一席之地。宝石矿物学及谱学特征研究有助于青金石的鉴定及其仿制品鉴别,并为其品质分级提供技术支撑。本文选取3件不同品质的青金石样品,利用宝石显微镜、红外光谱仪、激光拉曼光谱仪、紫外-可见光谱仪等对其进行测试,综合分析其矿物组成特征及谱学特征。结果显示,3件样品的矿物组成有较明显的差异:样品1主要矿物为青金石、方解石、黄铁矿、透辉石,含少量方钠石、榍石,品质中等;样品2主要矿物为青金石、方解石、黄铁矿、透辉石,含少量长石,品质较差;样品3仅见青金石、透辉石及少量黄铁矿,为高品质。3件样品的红外光谱差异不大,表现为青金石的架状硅酸盐结构及其结构通道的附加阴离子所致1 103、1 014、969、921、624、549、517、460、412 cm-1附近吸收峰。激光显微共聚焦拉曼光谱仪微区测试,3件样品均见257、544、1 092 cm-1处青金石的特征拉曼位移,最强峰出现在544 cm-1, 为S3-的对称伸缩振动所致。紫外-可见光谱表现为以600 nm为中心的宽带吸收带(与自由基离子S3-有关)以及400 nm附近弱吸收带(与SO42-及S2-有关),该特征吸收使青金石呈现蓝色或蓝紫色外观。

     

    Abstract: Lapis lazuli is a kind of blue mineral with a long history, which occupies a place in the history of human civilization. Study its gemmological and mineralogical characteristics not only helps the identification of lapis lazuli and its imitation products, but also provids technical support for its quality classification. In this paper, 3 lapis lazuli samples with different quality were selected and tested by gem microscope, infrared spectrometer, laser Raman spectrometer, and UV-Vis spectrometer, in order to analyze their mineral components and spectral characteristics comprehensively.The results showed that the mineral compoments of the samples are different obviously: the main mineral components of sample No.1 are lapis lazuli, calcite, pyrite, diopside, and a small amount of sodalite and sphene which indicates average quality. Sample No.2 with relatively poor quality is mainly composed of lapis lazuli, calcite, pyrite, diopside, with a small amount of feldspar. Only lapis lazuli, diopside and a small amount of pyrite are found in sample No.3, which is of high quality. The infrared spectra of the samples show few differences, and are mainly caused by the frame silicate structure of lapis lazuli and the additional anions of its structural channels, which locate around 1 103, 1 014, 969, 921, 624, 549, 517, 460 cm-1 and 412 cm-1. The characteristic Raman shifts of lapis lazuli samples are around 257, 544 cm-1 and 1 092 cm-1 and the strongest peak appears at 544 cm-1 which is caused by the symmetric stretching vibration of S3-. UV-Vis spectra of the lapis lazuli samples showed the broad band centered at 600 nm (associated with the free radical ion S3-) and the weak band around 400 nm (associated with SO42- and S2-), which give lapis lazuli a blue or bluish purple appearance.

     

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