苑执中, 亓利剑. HPHT和CVD培育钻石的鉴别简述及最新市场分析[J]. 宝石和宝石学杂志(中英文), 2021, 23(6): 40-50. DOI: 10.15964/j.cnki.027jgg.2021.06.004
引用本文: 苑执中, 亓利剑. HPHT和CVD培育钻石的鉴别简述及最新市场分析[J]. 宝石和宝石学杂志(中英文), 2021, 23(6): 40-50. DOI: 10.15964/j.cnki.027jgg.2021.06.004
YUAN Joe C.C., QI Lijian. A Brief Description of Identification Methods of HPHT and CVD Lab-Grown Diamonds and the Latest Market Analysis[J]. Journal of Gems & Gemmology, 2021, 23(6): 40-50. DOI: 10.15964/j.cnki.027jgg.2021.06.004
Citation: YUAN Joe C.C., QI Lijian. A Brief Description of Identification Methods of HPHT and CVD Lab-Grown Diamonds and the Latest Market Analysis[J]. Journal of Gems & Gemmology, 2021, 23(6): 40-50. DOI: 10.15964/j.cnki.027jgg.2021.06.004

HPHT和CVD培育钻石的鉴别简述及最新市场分析

A Brief Description of Identification Methods of HPHT and CVD Lab-Grown Diamonds and the Latest Market Analysis

  • 摘要: HPHT和CVD培育钻石与天然钻石有着相同的成分和物化性质,唯有生长时的环境、微量元素不同,培育钻石与天然钻石的鉴别特征至今没有一种仪器可以完全分辨出来,需要多种仪器,主要包括强磁吸附、显微放大观察、UV-Vis-NIR、深紫外光、光致发光光谱、正交偏光显微镜、磷光、热导仪、透射电子显微镜、红外光谱等测试方法分别找出微小差异,才可完全鉴别。本文列出各种仪器或方式鉴别特征予以说明。利用UV-Vis-NIR光谱中N3色心415 nm吸收峰;CVD钻石光致发光光谱中737 nm峰;CVD培育钻石在正交偏光下异常双折射条纹特征;HPHT培育钻石具有强蓝色磷光,CVD培育钻石具有中、弱磷光或无发光;热导仪部分HPHT培育钻石显示MOISSANITE,部分显示DIAMOND;在红外光谱未经HPHT改色的CVD钻石,在6 855、7 229、7 355 cm-1范围有数个C-H峰,经HPHT改色后这些峰消失。培育钻石业者除了首饰用途以外,必须积极开发工业用途才能够使培育钻石市场长久生存。

     

    Abstract: HPHT, CVD lab-grown diamonds and natural diamonds have the same composition and physical and chemical properties, only the environment and trace elements during growth are different. There is no instrument that can fully distinguish lab-grown diamonds from natural diamounds, and multiple types are needed. Instruments or methods include: strong magnetic, microscopic observation, UV-Vis-NIR, deep ultraviolet light, PL, cross-polarization microscope, phosphorescence, thermal conductivity meter, transmission electron microscope, infrared spectroscopy and other cross-comparisons to find out separately of small differences so that the lab-grown diamonds can be fully identified. This article lists and illustrates the identification characteristics of various instruments or methods. UV-Vis-NIR spectrum N3 colour center at 415 nm absorption peak; CVD diamond PL spectrum has a 737 nm peak of Si-V center; CVD lab-grown diamonds under crossed polarization can show a variety of abnormal birefringence fringes; HPHT lab-grown diamonds under phosphorescence will have strong blue luminescence, and CVD lab-grown diamonds will have medium, weak or no luminescence; in thermal conductivity meter test, some HPHT diamonds show MOISSANITE, and some show DIAMOND; CVD diamonds treated by HPHT show infrared spectrum in the range of 6 855, 7 229 cm-1 and 7 355 cm-1, revealing several C-H peaks, and these peaks disappear after HPHT colour treatment. In addition to the use of jewelry, the lab-grown diamond industry must actively develop industrial uses in order to survive for long time.

     

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