一种与绿松石相似的染色玛瑙的宝石学特征

Gemmological Characteristic of Dyed Agate Similar to Turquoise

  • 摘要: 近期,市场上出现一种与高品质绿松石十分相似的翠绿色玛瑙,商业名为“绿松玛瑙”。采用常规宝石学测试,傅里叶变换红外光谱仪、显微激光拉曼光谱仪、X射线荧光光谱仪及紫外-可见光分光度计,对其基本宝石学特征、化学成分、谱学特征及颜色成因等进行分析。结果表明,该种玛瑙的绿色分布不均,颜色仅存于表面,染色剂呈现由外至内扩散特点; X射线荧光光谱分析显示该玛瑙主量元素为Si,含有少量Al、Mg、Na元素及微量Mn、Fe、Cr等元素,样品表面Cr元素含量高于内部; 红外吸收光谱与石英的一致,可见有机物的特征吸收峰; 拉曼光谱显示α-石英和斜硅石的特征峰; 紫外-可见光谱显示267 nm附近的Cr6+的特征吸收带和八面体场中的Cr3+离子d-d跃迁所致的吸收带。该“绿松玛瑙”样品并非商家宣称的天然玛瑙,其绿色是经含Cr染色剂染色所致,根据国家标准(GB/T 16552—2017)规定,应将其定名为玛瑙。

     

    Abstract: Recently, a kind of emerald green gemstone named "Turquoise agate" appeared in the market which is similar to the high-quality turquoise. In this paper, the gemmological characteristics, mineral components, spectral characteristics and colour genesis of the green agate were determined by Fourier transform infrared spectrometer, Raman spectrometer, X-ray fluorescence spectrometer and UV-visible spectrophotometer. The results showed that the green colour is unevenly distributed on the surface of the sample which was caused by the dye diffusion from the outside to the inside. X-ray fluorescence spectra revealed that the main chemical composition of the sample is Si, with a small amount of Al, Mg, Na and trace elements such as Mn, Fe, Cr. There is a higher concentration of Cr in the green part of the sample. Characteristic peaks of the sample in FTIR were matched with the quartz. Meanwhile, the absorption bands caused by organic matter were observed. Raman spectra of the samples showed the characteristic peaks of alpha quartz and oblique silica. UV-Vis spectra showed that the green agate sample has the characteristic absorption band of Cr6+ near 267 nm and other bands caused by the d-d transition of Cr3+ ion in the octahedral field. In conclusion, the sample is not a natural agate as claimed by the merchants, but an enhanced gemstone. Its green colour is caused by dyeing with Cr-containing stain. According to the GB/T 16552-2017, it should be named as agate.

     

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