HPHT新合成Ⅱa型钻石包裹体与杂质特征及其对鉴定的指示

Spectroscopic Feature and Identification Application of the Impurity and Inclusion in Type Ⅱa HPHT Synthetic Diamond

  • 摘要: 近年来, 中国已成为Ⅱa型高压高温(HPHT)合成钻石的第一生产大国, Ⅱa型合成钻石的鉴定成为一项充满挑战的工作。为了解不同生产厂家的Ⅱa型HPHT合成钻石特征, 寻找其鉴定判别依据, 收集了我国高压高温(HPHT)生产厂家(HH、J、Z)的钻石样品, 对其中11粒Ⅱa型合成钻石典型样品的包裹体及杂质元素分布进行了放大观察及谱学测试。结果显示:(1)当Ⅱa型钻石在DiamondviewTM等设备下测试的荧光颜色与图像不能给出明确的鉴定证据时, 丝线状、管状、圆锥状包裹体特征, 无晶形的陨碳铁、赤铁矿、磁铁矿包裹体特征, 以及细小点状包裹体的分布特征, 可以作为判定新的HPHT合成钻石的参考依据; (2)在含有可测试杂质缺陷的样品中, 硼、镍等元素的杂质缺陷组合与分布特征, 可以作为新的HPHT合成钻石的辅助鉴定依据。

     

    Abstract: In recent years, China has become the largest producer of type Ⅱa colourless HPHT synthetic diamonds. And the identification of type Ⅱa HPHT synthetic diamond has become a challenging task. This research attempted to find the evidence of identification for type Ⅱa HPHT synthetic diamonds. Diamond samples from the high pressure and high temperature (HPHT) manufacturers in China (HH, J, Z) were collected, from which the inclusions and the distribution of impurities of 11 typical type Ⅱa diamond samples produced in the past three years were studied. Two main points of understanding were obtained: (1) When the fluorescent colour and image of type Ⅱa diamond under DiamondviewTM and other equipments can not give clear identification evidence, the conical, black thread-like or thin tubular inclusions, the distribution of fine point inclusions, shapeless cohenite, hematite, and magnetite inclusions can be used as the reference for determining the new HPHT synthetic diamonds. (2) Some samples have impurity defects which can be tested, and their emission peaks and distributions which are related to Ni and B can be used as the contributory characteristics for determining HPHT synthetic diamonds.

     

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