陕西汉中符山石玉的宝石矿物学特征研究

Gemmological and Mineralogical Characteristics of Idocrase Jade from Hanzhong, Shanxi Province

  • 摘要: 符山石,又名"加州玉",是近年来出现在市场的宝玉石品种,其密度、外观与翡翠非常相似,多被用来充当翡翠销售。本文采用常规宝石学测试、偏光显微镜观察、X射线粉末衍射分析、红外光谱、拉曼光谱、X射线荧光光谱分析等测试方法对产于陕西汉中市留坝县符山石玉样品的宝石学特征、矿物组成及谱学特征进行了研究。宝石学常规测试表明,汉中符山石玉的相对密度为3.29~3.47, 颜色多为绿色或黄绿色,个别样品中可见翠绿色团块。XRD测试结果显示汉中符山石玉的主要矿物组成为符山石,还含有少量的钙铝榴石、透辉石和绿泥石;红外光谱测试表明符山石玉的指纹区特征峰主要位于1 200~400 cm-1,其中1 200~800 cm-1吸收峰归属于Si-O-Si和O-Si-O伸缩振动所致,600 cm-1以下的吸收峰则由Si-O弯曲振动和M-O伸缩振动引起;显微拉曼光谱分析显示符山石玉在100~4 000 cm-1范围内有11~13个拉曼特征峰,同时测得样品中除符山石外,还包含有透辉石,绿泥石和钙铝榴石等;XRF分析表明,符山石玉中翠绿色团块处相比基质而言含有少量的Cr元素和V元素,推测其翠绿色由这两种元素导致。

     

    Abstract: Idocrase, also known as "California jade", is a variety of precious jade that has been appeared in the market in recent years. Its density and appearance are very similar to those of jadeite, and idocrase is mostly sold as jadeite product. The gemmological characteristics, mineral components and spectral characteristics of the samples collected from Liuba County, Hanzhong City, Shanxi Province, were studied by conventional gemmological tests and advanced instruments including polarizing microscope observation, X-ray powder diffraction analysis, infrared spectroscopy, Raman spectroscopy and X-ray fluorescence spectroscopy. The conventional gemmological testing results showed that the relative density of the idocrase samples range from 3.29 to 3.47 and most of the colour is green or yellowish green, and emerald green clump can be seen in some samples. XRD testing results showed that the main constituent mineral of idocrase from Hanzhong is idocrase, containing a small amount of grossularite, diopside and chlorite. The infrared spectra show that the characteristic peak in the fingerprint area of idocrase is mainly located between 1 200 to 400 cm-1, among which the absorption peak of 1 200 to 800 cm-1 belongs to the stretching vibration of Si-O-Si and O-Si-O, while the absorption peak under 600 cm-1 is caused by the bending vibration of Si-O and the stretching vibration of M-O.Microscopic Raman spectral showed that there are 11-13 characteristic Raman peaks in the range of 100 to 4 000 cm-1 in idocrase samples. Besides idocrase, the samples also include diopside, chlorite and grossularite. XRF analysis showed that the emerald green clump of idocrase contains a small amount of Cr and V compared with the matrix, and it is speculated that the emerald green is caused by these two elements.

     

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