缅甸Man Sin热粉色尖晶石的宝石学特征

Gemmological Characteristic of Hot Pink Spinel from Man Sin, Myanmar

  • 摘要: 近些年来,尖晶石以其独特的魅力走进人们的视野, 市场上对尖晶石的认可度也日益增高,特别是缅甸产出的热粉色(Hot pink)尖晶石。热粉色是尖晶石中一种特殊的色调,相比起纯正粉色,更偏于玫红甚至是正红色。然而随着此类品种在市场上走俏,目前对此种尖晶石的研究却少之又少。本文使用常规宝石学测试、DiamondViewTM、X射线荧光光谱仪、傅里叶变换红外光谱仪、紫外-可见光-近红外光谱仪等现代测试技术方法对缅甸Man Sin样品进行测试,并与坦桑尼亚热粉色尖晶石样品进行了对比研究。结果表明,缅甸Man Sin尖晶石样品的主要端元组分MgAl2O4,含有Cr、V、Fe、Zn、Ca等微量元素, 缅甸Man Sin尖晶石样品中Ca的质量分数为0.017%~0.034%,坦桑尼亚尖晶石样品Ca质量分数(2.877%)约是其平均数的56倍。紫外-可见光-近红外光谱中Cr3+引起686 nm的强吸收峰,V3+引起435 nm的吸收峰,Fe2+引起370 nm和585 nm吸收峰。两地热粉色尖晶石主要致色元素为Cr、V、Fe,但Ca质量分数的差异对产地鉴定提供了科学依据。

     

    Abstract: In recent years, spinel has come into people's sight with its unique charm, especiallythe hot pink spinel produced in Man Sin, Myanmar and Tanzania which has been greatly welcomed by market because of the craze of spinel.However, while the hot pink spinel has hit the market, the gemmological and spectroscopic studies of this gem are few. In order to underst and the gemmological and spectral characteristics of the hot pink spinel, X-ray fluorescence spectrometer (EDXRF) and Fourier transform spectrometer are used. The hot pink spinel samples were tested by modern testing techniques such as transform infrared spectroscopy and ultraviolet-visible-near infrared spectroscopy. The samples from Man Sin, Myanmar and Tanzania were compared. The results show that MgAl2O4, the main terminal component of Man Sin spinel samples, contains trace elements such as Cr, V, Fe, Zn and Ca. The mass fraction of Ca in Man Sin samples is 0.017%-0.034%, and that in Tanzania spinel samples, the mass fraction of Ca is about 56 times of its average. In ultraviolet-visible-near infrared spectra, Cr3+ causes 686 nm strong absorption peak, V3+ causes 435 nm absorption peak, and Fe2+ causes 370 nm and 585 nm absorption peak. The main chromogenic elements of hot pink spinel provide a scientific basis for the identification of localities because of the great differences in the contents of Cr, V, Fe and Ca.

     

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