越南安沛红宝石高温热处理与低温热处理工艺对比

Comparison of Heat Treatment at High Temperature and Low Temperature on Ruby from Yen Bai, Vietnam

  • 摘要: 对越南北部安沛地区带有蓝紫色调的红宝石原石按颜色饱和度进行分类高温热处理(1 600℃)和低温热处理(1 000℃)对比实验,拟定热处理温度、恒温时间、助熔剂条件等工艺参数,探究不同颜色样品的最佳热处理方案并比对温度参数下的适用范围。结果表明,在高温组改色实验中,红宝石样品的颜色及局部透明度均会有明显提高,浅紫红色、紫红色和深紫红色红宝石样品的最佳恒温时间随其颜色饱和度的增加从6 h、9 h到12 h依次增长,且添加硼砂和γ-Al2O3的混合助熔剂可以辅助吸附黄褐色色带处的杂质离子进而消除色带;在低温条件下,恒温12 h以上才能对越南红宝石的颜色起到较明显的改善作用。综合对比不同阶段的热处理效果发现:从透明度改善效果来看,具有开放裂隙的红宝石不适宜进行低温热处理;内部干净、仅颜色较差的红宝石样品,低温长时间加热与高温短时间加热的效果相近,更易被消费者所接受。热处理前后红宝石样品的紫外-可见吸收光谱测试验证了改色效果。

     

    Abstract: The comparative experiments of heat treatment at high temperature (1 600℃)and low temperature (1 000℃) on rubies with blue and violet hue from Yen Bai, Vietnam, were carried out according to the colour saturation.In addition, the main technology parameters were obtained, including the heat treatment temperature, holding time, and fluxing agent, to explore the best heat treatment scheme and compare the applicable range of the two sets of temperature parameters.The results showed that the colour and local transparency of the ruby samples improved obviously after heat treatment at high temperature.The optimum holding time of ruby samples with light purplish red, purplish red and deep purplish red got longer from 6 hours to 12 hours with the increase of the colour saturation.And the mixture of borax and strong adsorptive γ-Al2O3 can be used to help adsorb the foreign ions to remove the internal tawny bands effectively.While only keeping the holding time for over 12 hours can help improve the colour of the ruby samples obviously at low temperature.Contrasting the effect of heat treatment at different stages, ruby samples with fissures were not suitable for low temperature heat treatment in terms of transparency.For ruby samples with few fissures and off-colour, the effect of low temperature heating for a long time was similar to that at high temperature for a short heating time, however, from the view of market acceptance, low temperature heat treatment is more easily accepted due to its fuzzy identification characteristics.UV-Vis absorption spectra of ruby samples were tested for verifying the results of colour alteration.

     

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