一串杂色手排的未知鉴定

Identification of An Unknown Variegated Bracelet

  • 摘要: 贝壳是一种常见的首饰的材料,其种类繁多,经常被加工或处理成各种形状的饰物,难以判断其原始种类。本次对一串疑似“贝壳”的杂色手排样品进行未知鉴定,并将它与市场上常见的贝壳首饰进行对比研究,了解市场上贝壳首饰的主要品类及基本特征。利用折射仪、静水称重法等方法对手排及其它贝壳饰品进行基本宝石学特征测试,采用X射线荧光光谱仪、X射线粉末衍射仪、傅里叶变换红外光谱仪、拉曼光谱仪对其成分及谱学特征进行测试,最后利用扫描电子显微镜对内部结构进行观察。经过测试和分析,得出手排成分为方解石,呈细长板片状排布,整体呈近似放射状分布, 密度偏低,表面呈丝绢光泽,推测其取材于方解石型贝壳或贝壳方解石层。市场上的贝壳首饰主要矿物组成为文石,晶体呈砖墙状密集平行排布,它们的相对密度多高于手排样品,且表面显示珍珠光泽和晕彩。此外手排没有出现有机染料染色的特征,推测其颜色是由类胡萝卜素所致。

     

    Abstract: Shell is a kind of gem materials.There are many kinds of shells, which are usually cut and treated to different ornaments.Therefore it is difficult to identify their original shapes.Recently, a special kind of bracelet was found in the market.It is made of fourteen rectangular beads, which have four kinds of colour: Purple, orange, pink and white.It is opaque and has a laminated structure.The pink and orange part of bracelet have silky luster, and the bracelet has many things in common with shells.Therefore the study made comparison of the bracelet and other shell jewelries, which included Monetaria moneta, Pinctada margaritifera, Pincdata maxima, Trochus maculatus Linnaeus, Pteria penguin, etc.The fundamental gemmological characteristics of the bracelet and the other shell jewelries were tested by refractometer, balance, etc, and the composition and spectral features were measured by X-ray fluorescence spectrometer (XRF), X-ray diffraction (XRD), Fourier transformation infrared spectrometer (FTIR) and Raman spectrometer.The structure of the samples were analyzed by scanning electron microscope (SEM).According to the test results, the refractive index of the samples are all between 1.530 and 1.685, and the average refractive index of the sample is 1.57.The average relative density of the sample is 2.57, which is a little lower than the other shell jewelries.It may be caused by the difference of composition and structure, or by the influence of the hole on it.They have similar chemical composition, and are all rich in Ca and Sr.They have completely different mineral composition and structure.The bracelet is mainly made of calcite and it has a lath-like structure.The calcite crystal was arranged radically and has a low relative density and silky luster.The shell jewelries in the market are mainly made of aragonite and have a brick-wall structure, which is almost from nacre.The aragonite crystal was in parallel arrangement, which has higher relative density than the unknown sample, and has pearl luster and iridescence.The bracelet has not been dyed by organic dyes, and its colour may be caused by carotenoids according to Raman spectrum.In conclusion, the bracelet could be a kind of calcite-type shell or made from the calcite layer of a shell.The orange and pink colour may be directly caused by carotenoids, and the purple colour may be caused by carotenoids as well as protein complexation.

     

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