绿松石品质与水耦合关系及变温光谱学表征

Influence of Water on Turquoise Quality Characterized bySpectroscopy under Variable Temperatures

  • 摘要: 绿松石作为一种含水的铜、铝磷酸盐矿物,其矿物中的吸附水、结晶水以及结构水含量,与其结构的致密程度密切相关,对其质地具有一定的表征作用,进而对其颜色品质产生一定的影响。因此,在红外曲线拟合技术基础上,通过研究绿松石中“水”的变化情况作为绿松石品质研究的切入点,对绿松石质地及颜色的分类作半定量分析,进而为后续开展的绿松石品质分类提供科学理论依据。选取产自马鞍山的不同质地和颜色的绿松石原矿样品,通过25~400℃范围内变温加热实验,对绿松石中吸附水、结晶水和结构水的渐变逸出过程中的红外及紫外-可见吸收光谱进行测试,并采用曲线拟合法,分别对红外吸收光谱中结晶水及结构水的吸收谱带进行积分计算,结合绿松石的颜色坐标数值的变化情况,分析研究绿松石品质与其水分子之间的耦合关系及影响因素。结果表明,质地疏松绿松石中“水”峰的相对吸收强度及积分面积比质地致密绿松石明显偏高,并且质地疏松绿松石中结晶水和结构水的稳定性明显低于质地致密绿松石;蓝色调的绿松石往往较蓝绿色调及绿色调绿松石结构致密,低温环境下更不容易因失“水”而产生颜色变化。

     

    Abstract: Turquoise is a hydrous copper, aluminum phosphate mineral, and the content of the adsorbed water, crystal water and structural water in turquoise is closely related to its compactness and structure,which also contribute to its texture and the quality of colour. In this paper,infrared spectroscopy with curve fitting was used to study the changes in water features, in order to detect the quality of turquoise changing under the heat treatment. The turquoise with different textures and colours from Ma'anshan were chosen as our studying samples. The temperature of the heat treatment was set from 25-400℃ and the adsorbed water, crystal water, and structural water gradually escaping from turquoise when heating were characterized by infrared(IR) spectra and ultraviolet-visible(UV-Vis) spectra. According to curve fitting method, the areas of IR band for absorbed water and the IR band for crystal water were integrated. The change of colour coordinate values during the heat treatment was also measured by UV-Vis spectroscope. Combining the results of IR and the colour coordinate, the conclusion are:(1) The intensity of water related peaks in loose turquoise (bad quality) are higher than those in dense turquoise sample (good quality);(2)In the dense turquoise samples, the water features are more stable than those in the loose turquoise samples;(3) The blue turquoise are denser than the blue-green to green turquoises, and it is less likely to lose water under low temperature and change colour.

     

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